Alkene Polymerization Reactions with Transition Metal Catalysts

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

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  • Author : Yury Kissin
  • Publisher : Elsevier
  • Pages : 495 pages
  • ISBN : 9780080557991
  • Rating : 4/5 from 21 reviews
CLICK HERE TO GET THIS BOOKAlkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
  • Author : Yury Kissin
  • Publisher : Elsevier
  • Release : 10 March 2008
GET THIS BOOKAlkene Polymerization Reactions with Transition Metal Catalysts

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts
  • Author : Ray Hoff,Robert T. Mathers
  • Publisher : John Wiley & Sons
  • Release : 16 September 2010
GET THIS BOOKHandbook of Transition Metal Polymerization Catalysts

A one-stop resource for understanding and applying polymerization catalysts An edited volume featuring contributions from leading researchers, the Handbook of Transition Metal Polymerization Catalysts covers the design and synthesis of catalysts, and their applications in synthesis of polymers. Dealing with those polymerization catalysts that afford commercially acceptable yields of polymer with respect to catalyst mass and promising newer catalysts, this practical reference provides polymer and organic chemists with a comprehensive overview of the known methods for developing and applying these

Late Transition Metal Polymerization Catalysis

Late Transition Metal Polymerization Catalysis
  • Author : Bernhard Rieger,Lisa Saunders Baugh,Smita Kacker,Susanne Striegler
  • Publisher : John Wiley & Sons
  • Release : 06 March 2006
GET THIS BOOKLate Transition Metal Polymerization Catalysis

At the start of the 1950s, Ziegler and Natta discovered that simple metallorganic catalysts are capable of transforming olefins into linear polymers with highly ordered structures. This pioneering discovery was recognized with a Nobel Prize in 1963. In the 80s and 90s, the development of molecular defined metallocenes led to a renaissance for non-polar polyolefin materials. Designer catalysts allowed a greater precision in defining properties of the material. The past 10 years have seen the discovery of new catalysts based on late

Transition Metals and Organometallics as Catalysts for Olefin Polymerization

Transition Metals and Organometallics as Catalysts for Olefin Polymerization
  • Author : Walter Kaminsky,Hansjörg Sinn
  • Publisher : Springer Science & Business Media
  • Release : 06 December 2012
GET THIS BOOKTransition Metals and Organometallics as Catalysts for Olefin Polymerization

More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100°C, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly

Early Main Group Metal Catalysis

Early Main Group Metal Catalysis
  • Author : Sjoerd Harder
  • Publisher : John Wiley & Sons
  • Release : 03 February 2020
GET THIS BOOKEarly Main Group Metal Catalysis

Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well

Olefin Polymerization

Olefin Polymerization
  • Author : Walter Kaminsky
  • Publisher : Wiley-VCH
  • Release : 18 August 2006
GET THIS BOOKOlefin Polymerization

With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to

Comprehensive Organometallic Chemistry III

Comprehensive Organometallic Chemistry III
  • Author : Robert Crabtree
  • Publisher : Unknown Publisher
  • Release : 16 April 2021
GET THIS BOOKComprehensive Organometallic Chemistry III

Comprehensive Organometallic Chemistry, (COMC-III), Third Edition, 13 Volume Set is aimed at the specialist and non-specialist alike. It covers the major developments in the field in a carefully presented way with extensive cross-references. COMC-III provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Applications of organometallic chemistry continue to expand and this has been reflected by the significant increase in the number of volumes devoted to applications in

Metalorganic Catalysts for Synthesis and Polymerization

Metalorganic Catalysts for Synthesis and Polymerization
  • Author : Walter Kaminsky
  • Publisher : Springer Science & Business Media
  • Release : 06 December 2012
GET THIS BOOKMetalorganic Catalysts for Synthesis and Polymerization

45 years after the discovery of transition metals and organometallics as cocatalysts for the polymerization of olefins and for organic synthesis, these compounds have not lost their fascination. The birthday of Karl Ziegler, the great pioneer in this metalorganic catalysis, is now 100 years ago. Polyolefins and polydienes produced by Ziegler-Natta catalysis are the most important plastics and elastomers. New impulses for the polymerization of olefins have been brought about by highly active metallocenes and other single site catalysts. Just by changing

Metal-catalysis in Industrial Organic Processes

Metal-catalysis in Industrial Organic Processes
  • Author : Royal Society of Chemistry (Great Britain)
  • Publisher : Royal Society of Chemistry
  • Release : 16 April 2021
GET THIS BOOKMetal-catalysis in Industrial Organic Processes

Catalysis underpins most modern industrial organic processes. It has become an essential tool in creating a 'greener' chemical industry by replacing more traditional stoichiometric reactions, which have high energy consumption and high waste production, with mild processes which increasingly resemble Nature's enzymes. Metal-Catalysis in Industrial Organic Processes considers the major areas of the field and discusses the logic of using catalysis in industrial processes. This popular book, now available as softback, provides information on oxidation, hydrogenation, carbonylation, C-C bond formation,

Polymers as Aids in Organic Chemistry

Polymers as Aids in Organic Chemistry
  • Author : N. K. Mathur,Nawal Kishore Mathur,Narendra Kumar Mathur,Chander Kumar Narang,C. K. Narang,Ross Ernest Williams,Ralph Edward Williams,R. E. Williams
  • Publisher : Unknown Publisher
  • Release : 16 April 1980
GET THIS BOOKPolymers as Aids in Organic Chemistry

Polymers as Aids in Organic Chemistry covers the broad classifications and application of polymers in organic chemistry. This book is organized into 15 chapters that focus on the transformation of polymers and their role in other reagents that must be easily separated from their final product. After a brief introduction to polymer chemistry, the book presents a tabulation of the various types of polymers that have been used and the methods for their characterization. It then discusses the use of polymers

Polymer Reactions

Polymer Reactions
  • Author : Geoffrey Allen,J. C. Bevington,Geoffrey C. Eastmond
  • Publisher : Pergamon
  • Release : 16 April 1989
GET THIS BOOKPolymer Reactions

Hardbound. Volume 6 reviews polymer reactions with 23 chapters discussing various aspects of the subject.