Alkene Polymerization Reactions with Transition Metal Catalysts

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

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  • Author : Yury Kissin
  • Publisher : Elsevier
  • Pages : 495 pages
  • ISBN : 9780080557991
  • Rating : 4/5 from 21 reviews
CLICK HERE TO GET THIS BOOKAlkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
  • Author : Yury Kissin
  • Publisher : Elsevier
  • Release : 10 March 2008
GET THIS BOOKAlkene Polymerization Reactions with Transition Metal Catalysts

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
  • Author : Y. V. Kissin
  • Publisher : Elsevier Science & Technology
  • Release : 30 November 2021
GET THIS BOOKAlkene Polymerization Reactions with Transition Metal Catalysts

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts
  • Author : Ray Hoff
  • Publisher : John Wiley & Sons
  • Release : 20 April 2018
GET THIS BOOKHandbook of Transition Metal Polymerization Catalysts

Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield

Introduction to Industrial Polypropylene

Introduction to Industrial Polypropylene
  • Author : Dennis B. Malpass,Elliot Band
  • Publisher : John Wiley & Sons
  • Release : 02 July 2012
GET THIS BOOKIntroduction to Industrial Polypropylene

This introductory text is an important resource for new engineers, chemists, students, and chemical industry personnel to understand the technical aspects of polypropylene which is the 2nd largest synthetics polymer in manufactured output. The book considers the following topics: What are the principal types of polypropylene and how do they differ? What catalysts are used to produce polypropylene and how do they function? What is the role of cocatalysts and how have they evolved over the years? How are industrial

Carraher's Polymer Chemistry, Tenth Edition

Carraher's Polymer Chemistry, Tenth Edition
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release : 12 October 2017
GET THIS BOOKCarraher's Polymer Chemistry, Tenth Edition

Carraher's Polymer Chemistry, Tenth Edition integrates the core areas of polymer science. Along with updating of each chapter, newly added content reflects the growing applications in Biochemistry, Biomaterials, and Sustainable Industries. Providing a user-friendly approach to the world of polymeric materials, the book allows students to integrate their chemical knowledge and establish a connection between fundamental and applied chemical information. It contains all of the elements of an introductory text with synthesis, property, application, and characterization. Special sections in each

Handbook of Industrial Polyethylene and Technology

Handbook of Industrial Polyethylene and Technology
  • Author : Mark A. Spalding,Ananda Chatterjee
  • Publisher : John Wiley & Sons
  • Release : 12 October 2017
GET THIS BOOKHandbook of Industrial Polyethylene and Technology

This handbook provides an exhaustive description of polyethylene. The 50+ chapters are written by some of the most experienced and prominent authors in the field, providing a truly unique view of polyethylene. The book starts with a historical discussion on how low density polyethylene was discovered and how it provided unique opportunities in the early days. New catalysts are presented and show how they created an expansion in available products including linear low density polyethylene, high density polyethylene, copolymers, and polyethylene

Introduction to Polymer Chemistry

Introduction to Polymer Chemistry
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release : 06 January 2017
GET THIS BOOKIntroduction to Polymer Chemistry

Introduction to Polymer Chemistry provides undergraduate students with a much-needed, well-rounded presentation of the principles and applications of natural, synthetic, inorganic, and organic polymers. With an emphasis on the environment and green chemistry and materials, this fourth edition continues to provide detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, elastomers, adhesives, coatings, fibers, plastics, blends, caulks, composites, and ceramics. Building on undergraduate work in foundational courses, the text fulfills the American Chemical Society Committee on Professional

Introduction to Polymer Chemistry, Third Edition

Introduction to Polymer Chemistry, Third Edition
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release : 04 December 2012
GET THIS BOOKIntroduction to Polymer Chemistry, Third Edition

Continuing the tradition of its previous editions, the third edition of Introduction to Polymer Chemistry provides a well-rounded presentation of the principles and applications of natural, synthetic, inorganic, and organic polymers. With an emphasis on the environment and green chemistry and materials, this third edition offers detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, biomacromolecules, elastomers, adhesives, coatings, fibers, plastics, blends, caulks, composites, and ceramics. Using simple fundamentals, the book demonstrates how the basic principles of

Carraher's Polymer Chemistry, Ninth Edition

Carraher's Polymer Chemistry, Ninth Edition
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release : 19 April 2016
GET THIS BOOKCarraher's Polymer Chemistry, Ninth Edition

Most of the advancements in communication, computers, medicine, and air and water purity are linked to macromolecules and a fundamental understanding of the principles that govern their behavior. These fundamentals are explored in Carraher's Polymer Chemistry, Ninth Edition. Continuing the tradition of previous volumes, the latest edition provides a well-rounded presentation of the principles and applications of polymers. With an emphasis on the environment and green chemistry and materials, this edition offers detailed coverage of natural and synthetic giant molecules,

Carraher's Polymer Chemistry, Eighth Edition

Carraher's Polymer Chemistry, Eighth Edition
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release : 13 October 2010
GET THIS BOOKCarraher's Polymer Chemistry, Eighth Edition

Updated to reflect a growing focus on green chemistry in the scientific community and in compliance with the American Chemical Society’s Committee on Professional Training guidelines, Carraher’s Polymer Chemistry, Eighth Edition integrates the core areas that contribute to the growth of polymer science. It supplies the basic understanding of polymers essential to the training of science, biomedical, and engineering students. New in the Eighth Edition: Updating of analytical, physical, and special characterization techniques Increased emphasis on carbon nanotubes,

Zeolites and Related Materials: Trends Targets and Challenges(SET)

Zeolites and Related Materials: Trends Targets and Challenges(SET)
  • Author : Antoine Gedeon,Pascale Massiani,Florence Babonneau
  • Publisher : Elsevier
  • Release : 19 August 2008
GET THIS BOOKZeolites and Related Materials: Trends Targets and Challenges(SET)

The present book "Zeolites and Related Materials: Trends, Targets and Challenges" reports the communications that have been presented at the 4th International FEZA (Federation of European Zeolite Associations) Conference in Paris, September 3-6, 2008. It gives an excellent overview of the present state of the art of ordered nanoporous solids including zeolites as well as synthetic layered materials (clays), nanosized molecular sieves, ordered mesoporous solids, metal-organic-framework compounds (MOFs), carbons, etc. with emphasis on the synthesis, comprehensive characterization and advanced applications. The

Ullmann's Polymers and Plastics

Ullmann's Polymers and Plastics
  • Author : Wiley-VCH
  • Publisher : John Wiley & Sons
  • Release : 18 March 2016
GET THIS BOOKUllmann's Polymers and Plastics

Your personal Ullmann's: Chemical and physical characteristics, production processes and production figures, main applications, toxicology and safety information are all to be found here in one single resource - bringing the vast knowledge of the Ullmann's Encyclopedia to the desks of industrial chemists and chemical engineers. The ULLMANN’S perspective on polymers and plastics brings reliable information on more than 1500 compounds and products straight to your desktop Carefully selected “best of” compilation of 61 topical articles from the Encyclopedia of Industrial

Olefin Polymerization

Olefin Polymerization
  • Author : Walter Kaminsky
  • Publisher : Wiley-VCH
  • Release : 18 August 2006
GET THIS BOOKOlefin Polymerization

With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to

Inorganic Reactions and Methods, The Formation of Bonds to Transition and Inner-Transition Metals

Inorganic Reactions and Methods, The Formation of Bonds to Transition and Inner-Transition Metals
  • Author : A. P. Hagen
  • Publisher : John Wiley & Sons
  • Release : 17 September 2009
GET THIS BOOKInorganic Reactions and Methods, The Formation of Bonds to Transition and Inner-Transition Metals

Boasting numerous industrial applications, inorganic chemistry forms the basis for research into new materials and bioinorganic compounds such as calcium that act as biological catalysts. Now complete, this highly acclaimed series presents current knowledge in all areas of inorganic chemistry, including chemistry of the elements; organometallic, polymeric and solid-state materials; and compounds relevant to bioinorganic chemistry.