Alkene Polymerization Reactions with Transition Metal Catalysts

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

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  • Author : Yury Kissin
  • Publisher : Elsevier
  • Pages : 495 pages
  • ISBN : 9780080557991
  • Rating : 4/5 from 21 reviews
CLICK HERE TO GET THIS BOOKAlkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
  • Author : Yury Kissin
  • Publisher : Elsevier
  • Release : 10 March 2008
GET THIS BOOKAlkene Polymerization Reactions with Transition Metal Catalysts

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts
  • Author : Ray Hoff,Robert T. Mathers
  • Publisher : John Wiley & Sons
  • Release : 16 September 2010
GET THIS BOOKHandbook of Transition Metal Polymerization Catalysts

A one-stop resource for understanding and applying polymerization catalysts An edited volume featuring contributions from leading researchers, the Handbook of Transition Metal Polymerization Catalysts covers the design and synthesis of catalysts, and their applications in synthesis of polymers. Dealing with those polymerization catalysts that afford commercially acceptable yields of polymer with respect to catalyst mass and promising newer catalysts, this practical reference provides polymer and organic chemists with a comprehensive overview of the known methods for developing and applying these

Late Transition Metal Polymerization Catalysis

Late Transition Metal Polymerization Catalysis
  • Author : Bernhard Rieger,Lisa Saunders Baugh,Smita Kacker,Susanne Striegler
  • Publisher : John Wiley & Sons
  • Release : 06 March 2006
GET THIS BOOKLate Transition Metal Polymerization Catalysis

At the start of the 1950s, Ziegler and Natta discovered that simple metallorganic catalysts are capable of transforming olefins into linear polymers with highly ordered structures. This pioneering discovery was recognized with a Nobel Prize in 1963. In the 80s and 90s, the development of molecular defined metallocenes led to a renaissance for non-polar polyolefin materials. Designer catalysts allowed a greater precision in defining properties of the material. The past 10 years have seen the discovery of new catalysts based on late

Carraher's Polymer Chemistry, Ninth Edition

Carraher's Polymer Chemistry, Ninth Edition
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release : 05 September 2013
GET THIS BOOKCarraher's Polymer Chemistry, Ninth Edition

Most of the advancements in communication, computers, medicine, and air and water purity are linked to macromolecules and a fundamental understanding of the principles that govern their behavior. These fundamentals are explored in Carraher's Polymer Chemistry, Ninth Edition. Continuing the tradition of previous volumes, the latest edition provides a well-rounded presentation of the principles and applications of polymers. With an emphasis on the environment and green chemistry and materials, this edition offers detailed coverage of natural and synthetic giant molecules,

Activation Of Alkenes And Alkynes

Activation Of Alkenes And Alkynes
  • Author : M.M. Taqui Khan
  • Publisher : Elsevier
  • Release : 02 December 2012
GET THIS BOOKActivation Of Alkenes And Alkynes

Homogeneous Catalysis by Metal Complexes, Volume II: Activation of Alkenes and Alkynes reviews and systematizes the chemistry of metal ion activation of alkenes and alkynes. The book presents the migration of ? bonds; the oxo reaction; and the hydrosilation of alkenes and alkynes. The text also covers topics on the oxidation of alkenes and alkynes, as well as the multiple insertion reactions of alkenes and alkynes.

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts
  • Author : Ray Hoff
  • Publisher : John Wiley & Sons
  • Release : 08 May 2018
GET THIS BOOKHandbook of Transition Metal Polymerization Catalysts

Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield

Transition Metals and Organometallics as Catalysts for Olefin Polymerization

Transition Metals and Organometallics as Catalysts for Olefin Polymerization
  • Author : Walter Kaminsky,Hansjörg Sinn
  • Publisher : Springer Science & Business Media
  • Release : 06 December 2012
GET THIS BOOKTransition Metals and Organometallics as Catalysts for Olefin Polymerization

More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100°C, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly

Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides

Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides
  • Author : Anant R. Kapdi,Debabrata Maiti,Yogesh S. Sanghvi
  • Publisher : Elsevier
  • Release : 04 June 2018
GET THIS BOOKPalladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides

Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides describes the procedures and protocols related to the modification of nucleosides, nucleotides and oligonucleotides via Pd-mediated cross-coupling processes. The book highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist this development. Users will find key synthetic protocols for these reactions in this latest volume in the Latest Trends in Palladium Chemistry series. As most of the research in the field of antiviral agents has centered on the

Comprehensive Organometallic Chemistry III

Comprehensive Organometallic Chemistry III
  • Author : Robert Crabtree
  • Publisher : Unknown Publisher
  • Release : 26 January 2021
GET THIS BOOKComprehensive Organometallic Chemistry III

Comprehensive Organometallic Chemistry, (COMC-III), Third Edition, 13 Volume Set is aimed at the specialist and non-specialist alike. It covers the major developments in the field in a carefully presented way with extensive cross-references. COMC-III provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Applications of organometallic chemistry continue to expand and this has been reflected by the significant increase in the number of volumes devoted to applications in

Metalorganic Catalysts for Synthesis and Polymerization

Metalorganic Catalysts for Synthesis and Polymerization
  • Author : Walter Kaminsky
  • Publisher : Springer Science & Business Media
  • Release : 06 December 2012
GET THIS BOOKMetalorganic Catalysts for Synthesis and Polymerization

45 years after the discovery of transition metals and organometallics as cocatalysts for the polymerization of olefins and for organic synthesis, these compounds have not lost their fascination. The birthday of Karl Ziegler, the great pioneer in this metalorganic catalysis, is now 100 years ago. Polyolefins and polydienes produced by Ziegler-Natta catalysis are the most important plastics and elastomers. New impulses for the polymerization of olefins have been brought about by highly active metallocenes and other single site catalysts. Just by changing

Monitoring Polymerization Reactions

Monitoring Polymerization Reactions
  • Author : Wayne F. Reed,Alina M. Alb
  • Publisher : John Wiley & Sons
  • Release : 02 December 2013
GET THIS BOOKMonitoring Polymerization Reactions

Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics,

Homogeneous Catalysis with Compounds of Rhodium and Iridium

Homogeneous Catalysis with Compounds of Rhodium and Iridium
  • Author : R. Dickson
  • Publisher : Springer Science & Business Media
  • Release : 30 September 1985
GET THIS BOOKHomogeneous Catalysis with Compounds of Rhodium and Iridium

Some years ago, I agreed to contribute a volume to the Academic Press 'Organo metallic Chemistry' series - the metals to be covered were rhodium and iridium. Initially, my plan was to discuss both the fundamental organometallic chemistry and applications in organic synthesis. When the first draft of the manuscript was complete, it was apparent that I had exceeded my allowance of pages by a huge amount. It was then that I decided that the catalysis section warranted separate treatment.

Olefin Polymerization

Olefin Polymerization
  • Author : Walter Kaminsky
  • Publisher : Wiley-VCH
  • Release : 18 August 2006
GET THIS BOOKOlefin Polymerization

With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to