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Metal clusters, an intermediate state between molecules and the extended solid, show peculiar bonding and reactivity patterns. Their significance is critical to many areas, including air pollution, interstellar matter, clay minerals, photography, catalysis, quantum dots, and virus crystals. In Aromaticity and Metal Clusters, dozens of international experts explore not only the basic aspects of aromaticity, but also the structures, properties, reactivity, stability, and other consequences of the aromaticity of a variety of metal clusters. Although the concept of aromaticity has
Heterocyclic chemistry is the biggest branch of chemistry covering two-thirds of the chemical literature. Aromaticity in Heterocyclic Compounds covers hot topics of frontier research summarized by reputed scientists in the field.
Aromaticity: Modern Computational Methods and Applications reviews state-of-the-art computational methods in this field and discusses their applicability for evaluating the aromaticity of a system. In addition to covering aromaticity for typical organic molecules, this volume also explores systems possessing transition metals in their structures, macrocycles and even transition structures. The influence of the aromaticity on the properties of these species (including the structure, magnetic properties and reactivity) is highlighted, along with potential applications in fields including materials science and medicinal
Originally published in 1969, this book analyses the special properties of benzene and its derivatives, which give them their distinct aromatic character. The text first discusses the structure of benzene, including the light shed on it by physical methods and wave mechanics, and the structure of polycyclic benzenoid hydrocarbons and heterocyclic aromatic compounds. Aromaticity is defined as a function of the electronic structure of the molecule or ion in question and it is shown that this has important consequences in respect
A comprehensive review of the essential characteristics and properties of aromaticity, written by leaders of the field Aromaticity and Antiaromaticity: Concepts and Applications offers an authoritative guide that examines the geometrical, electronic, magnetic, thermodynamic characteristics and reactivity properties of aromaticity and provides insight into its nature. Whilst the concept of aromaticity has been known for nearly two centuries, there was no way to accurately measure it nor a theoretical formula to calculate it. The book offers a detailed review of
The understanding of benzene and hence of all aromatic compounds, proved to be so important for both applied chemistry and Pharmacy. Many important chemical compounds are derived from benzene by replacing one or more of its hydrogen atoms with another functional group. In heterocycles, carbon atoms in the benzene ring are replaced with other elements. In this book the chemical nature of benzene and aromatic reaction describes smoothly.