Direct Synthesis of Coordination and Organometallic Compounds

This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objective of this book is to acquaint the readers with the mentioned achievements. Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans. There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and &bgr;-diketones).

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  • Author : A.D. Garnovskii
  • Publisher : Elsevier
  • Pages : 244 pages
  • ISBN : 9780080530444
  • Rating : 4/5 from 21 reviews
CLICK HERE TO GET THIS BOOKDirect Synthesis of Coordination and Organometallic Compounds

Direct Synthesis of Coordination and Organometallic Compounds

Direct Synthesis of Coordination and Organometallic Compounds
  • Author : A.D. Garnovskii,B.I. Kharisov
  • Publisher : Elsevier
  • Release : 13 August 1999
GET THIS BOOKDirect Synthesis of Coordination and Organometallic Compounds

This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of

Direct Synthesis of Metal Complexes

Direct Synthesis of Metal Complexes
  • Author : B.I. Kharisov
  • Publisher : Elsevier
  • Release : 19 April 2018
GET THIS BOOKDirect Synthesis of Metal Complexes

Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment

Carbonylation

Carbonylation
  • Author : H.M. Colquhoun,D.J. Thompson,M.V. Twigg
  • Publisher : Springer Science & Business Media
  • Release : 29 June 2013
GET THIS BOOKCarbonylation

Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide as the source of the carbonyl group has seen exceptional progress, and this carbonylation chemistry is being used increasingly in research and on a larger scale for fine chemicals production.

Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity

Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity
  • Author : H. Geissbühler,G. T. Brooks,P. C. Kearney
  • Publisher : Elsevier
  • Release : 22 October 2013
GET THIS BOOKSynthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity

Advances in Pesticide Science, Part 2: Synthesis of Pesticides, Chemical Structure and Biological Activity, Natural Products with Biological Activity is a collection of papers presented at the Fourth International Congress of Pesticide Chemistry, held in Zurich, Switzerland on July 24-28, 1978. This book is composed of forty eight chapters, and begins with the synthesis of pesticides. The succeeding chapters deal with heterocyclic synthesis by rearrangement, synthesis and transformations of nitrogen and sulphurcontaining bicyclic heterocyclic systems. These topics are followed by discussions on

Synthetic Coordination and Organometallic Chemistry

Synthetic Coordination and Organometallic Chemistry
  • Author : Alexander D. Garnovskii,Boris I. Kharissov
  • Publisher : CRC Press
  • Release : 25 April 2003
GET THIS BOOKSynthetic Coordination and Organometallic Chemistry

This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-,

Metal Mediated Template Synthesis of Ligands

Metal Mediated Template Synthesis of Ligands
  • Author : Otilia Costisor
  • Publisher : World Scientific
  • Release : 08 December 2021
GET THIS BOOKMetal Mediated Template Synthesis of Ligands

This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students,

Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds

Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds
  • Author : A.J.L. Pombeiro,J.A. McCleverty
  • Publisher : Springer Science & Business Media
  • Release : 02 February 2012
GET THIS BOOKMolecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds

The use of electrochemical techniques by chemists, particularly those who regard themselves as "inorganic" coordination chemists, has undergone a very rapid growth in the last 15-20 years. The techniques, as dassically applied to inorganic species, had their origins in analytical chemistry, and the methodology had assumed, until the mid 60s, more importance than the chemiStry. However, the growth of interest in coordination compounds (including organometallic complexes) having unusually rich of electron-transfer in bio-inorganic redox properties, and in the understanding species,

Handbook on Applications of Ultrasound

Handbook on Applications of Ultrasound
  • Author : Dong Chen,Sanjay K. Sharma,Ackmez Mudhoo
  • Publisher : CRC Press
  • Release : 26 July 2011
GET THIS BOOKHandbook on Applications of Ultrasound

Ultrasonic irradiation and the associated sonochemical and sonophysical effects are complementary techniques for driving more efficient chemical reactions and yields. Sonochemistry—the chemical effects and applications of ultrasonic waves—and sustainable (green) chemistry both aim to use less hazardous chemicals and solvents, reduce energy consumption, and increase product selectivity. A comprehensive collection of knowledge, Handbook on Applications of Ultrasound covers the most relevant aspects linked to and linking green chemistry practices to environmental sustainability through the uses and applications of

Green Synthesis of Silver Nanomaterials

Green Synthesis of Silver Nanomaterials
  • Author : Kamel A. Abd-Elsalam
  • Publisher : Elsevier
  • Release : 01 November 2021
GET THIS BOOKGreen Synthesis of Silver Nanomaterials

Green Synthesis of Silver Nanomaterials illustrates how to biologically scale up silver nanoparticle synthesis. This book covers green synthesis of silver nanomaterials, via plants, agricultural waste, fungi, and microorganisms. Sections cover the synthesis and characterization of chemical and green synthesis, various types of silver nanomaterialism, the ability of different fungal species, such as filamentous fungi, to produce silver nanoparticles, the microbial synthesis of silver NMs, biosynthesis mechanisms, toxicity, fate and commercialization. As examples, greener pathways and mechanisms, toxicity of silver

Chemistry of Zeolites and Related Porous Materials

Chemistry of Zeolites and Related Porous Materials
  • Author : Ruren Xu,Wenqin Pang,Jihong Yu,Qisheng Huo,Jiesheng Chen
  • Publisher : John Wiley & Sons
  • Release : 29 May 2009
GET THIS BOOKChemistry of Zeolites and Related Porous Materials

Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks.

Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 2

Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 2
  • Author : Tsuneo Imamoto
  • Publisher : Georg Thieme Verlag
  • Release : 14 May 2014
GET THIS BOOKScience of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 2

Science of Synthesis provides a critical review of the synthetic methodology developed from the early 1800s to date for the entire field of organic and organometallic chemistry. As the only resource providing full-text descriptions of organic transformations and synthetic methods as well as experimental procedures, Science of Synthesis is therefore a unique chemical information tool. Over 1000 world-renowned experts have chosen the most important molecular transformations for a class of organic compounds and elaborated on their scope and limitations. The systematic,

Transition metal Organometallics In Organic Synthesis

Transition metal Organometallics In Organic Synthesis
  • Author : Howard Alper
  • Publisher : Elsevier
  • Release : 02 December 2012
GET THIS BOOKTransition metal Organometallics In Organic Synthesis

Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis.

Organometallic Chemistry

Organometallic Chemistry
  • Author : E W Abel,F G A Stone
  • Publisher : Royal Society of Chemistry
  • Release : 31 October 2007
GET THIS BOOKOrganometallic Chemistry

Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects

Chemistry Under Extreme and Non-Classical Conditions

Chemistry Under Extreme and Non-Classical Conditions
  • Author : Rudi van Eldik,Colin D. Hubbard
  • Publisher : John Wiley & Sons
  • Release : 06 December 1996
GET THIS BOOKChemistry Under Extreme and Non-Classical Conditions

The very best and latest advances compiled in a single volume-an ideal resource for graduate students and researchers . . . Here is the perfect introduction to chemistry under extreme or non-classical conditions, including use of high temperature species, high pressure, supercritical media, sonochemistry, and microwave chemistry. Written by leading experts in their respective fields, this unique text applies a unified approach to each method, including background, instrumentation, examples, information on industrial applications (where relevant), and sources for further reading. Featured topics: * Chemical