Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. * Comprehensive listing of epoxide products * Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts * Analysis of the general strengths and weaknesses of varied catalytic systems * Detailed description of the mechanisms of reaction for classical and emerging catalysts

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  • Author : S. Ted Oyama
  • Publisher : Elsevier
  • Pages : 528 pages
  • ISBN : 9780080558011
  • Rating : 4/5 from 21 reviews
CLICK HERE TO GET THIS BOOKMechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis
  • Author : S. Ted Oyama
  • Publisher : Elsevier
  • Release : 13 October 2011
GET THIS BOOKMechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis
  • Author : S. Ted Oyama
  • Publisher : Elsevier
  • Release : 13 October 2011
GET THIS BOOKMechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and

Catalysis in Petrochemical Processes

Catalysis in Petrochemical Processes
  • Author : M.S. Matar,M.J. Mirbach,H.A. Tayim
  • Publisher : Springer Science & Business Media
  • Release : 31 December 1988
GET THIS BOOKCatalysis in Petrochemical Processes

The field of petrochemicals started some years ago with the simple addition reaction of water to propylene for the production of isopropyl alcohol. Currently, the petrochemical industry has become a multi-billion dollar enterprise which encompasses a wide field of chemical products. Almost all the basic organic reactions such as hydrogenation, alkylation, substitution, polymerization, etc. are utilized for the production of these chemicals. It may not, however, have been possible to establish this huge industry without the use of different catalysts.

Liquid Phase Aerobic Oxidation Catalysis

Liquid Phase Aerobic Oxidation Catalysis
  • Author : Shannon S. Stahl,Paul L. Alsters
  • Publisher : John Wiley & Sons
  • Release : 13 July 2016
GET THIS BOOKLiquid Phase Aerobic Oxidation Catalysis

The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts

Nanotechnology in Catalysis, 3 Volumes

Nanotechnology in Catalysis, 3 Volumes
  • Author : Bert Sels
  • Publisher : John Wiley & Sons
  • Release : 16 October 2017
GET THIS BOOKNanotechnology in Catalysis, 3 Volumes

Reflecting the R&D efforts in the field that have resulted in a plethora of novel applications over the past decade, this handbook gives a comprehensive overview of the tangible benefits of nanotechnology in catalysis. By bridging fundamental research and industrial development, it provides a unique perspective on this scientifically and economically important field. While the first three parts are devoted to preparation and characterization of nanocatalysts, the final three provide in-depth insights into their applications in the fine chemicals

Modern Heterogeneous Catalysis

Modern Heterogeneous Catalysis
  • Author : Rutger A. van Santen
  • Publisher : John Wiley & Sons
  • Release : 15 February 2017
GET THIS BOOKModern Heterogeneous Catalysis

Written by one of the world's leading experts on the topic, this advanced textbook is the perfect introduction for newcomers to this exciting field. Concise and clear, the text focuses on such key aspects as kinetics, reaction mechanism and surface reactivity, concentrating on the essentials. The author also covers various catalytic systems, catalysis by design, and activation-deactivation. A website with supplementary material offers additional figures, original material and references.

Industrial Catalytic Processes for Fine and Specialty Chemicals

Industrial Catalytic Processes for Fine and Specialty Chemicals
  • Author : Sunil S Joshi,Vivek V. Ranade
  • Publisher : Elsevier
  • Release : 12 April 2016
GET THIS BOOKIndustrial Catalytic Processes for Fine and Specialty Chemicals

Industrial Catalytic Processes for Fine and Specialty Chemicals provides a comprehensive methodology and state-of-the art toolbox for industrial catalysis. The book begins by introducing the reader to the interesting, challenging, and important field of catalysis and catalytic processes. The fundamentals of catalysis and catalytic processes are fully covered before delving into the important industrial applications of catalysis and catalytic processes, with an emphasis on green and sustainable technologies. Several case studies illustrate new and sustainable ways of designing catalysts and

Heterogeneous Catalysis in Organic Chemistry

Heterogeneous Catalysis in Organic Chemistry
  • Author : Gerard V. Smith,Ferenc Notheisz
  • Publisher : Academic Press
  • Release : 30 June 1999
GET THIS BOOKHeterogeneous Catalysis in Organic Chemistry

The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses. Most synthetic organic chemists use a variety of "protecting groups" which they attach to functional

Mechanisms in Homogeneous Catalysis

Mechanisms in Homogeneous Catalysis
  • Author : Brian Heaton
  • Publisher : John Wiley & Sons
  • Release : 06 March 2006
GET THIS BOOKMechanisms in Homogeneous Catalysis

While chemists using spectroscopic methods need to learn from the specialists, they do not normally read the spectroscopists' original papers. This book provides this very information -- summarizing some recent advances in the mechanistic understanding of metallocene polymerization catalysts and the role of NMR spectroscopy in these endeavors. Adopting a real practice-oriented approach, the authors focus on two of the most important spectroscopic techniques with two parts devoted to each of NMR and IR spectroscopy - as well as on

Catalysts for Fine Chemical Synthesis, Catalysis by Polyoxometalates

Catalysts for Fine Chemical Synthesis, Catalysis by Polyoxometalates
  • Author : Ivan Kozhevnikov
  • Publisher : Wiley
  • Release : 11 October 2002
GET THIS BOOKCatalysts for Fine Chemical Synthesis, Catalysis by Polyoxometalates

Whole journals are devoted to catalysis and books describe the various catalysts. However it is very difficult to find detailed protocols offering information on where to source catalysts, how to store them, how to activate them for the synthesis, how to perform the actual synthesis and how to recycle the catalysts out of the synthesis process. This new series of books (accompanied by CD-ROM) addresses all these issues. Each volume publishes approximately 40 detailed procedures and makes use of different catalysts.

Vanadium Catalysis

Vanadium Catalysis
  • Author : Manas Sutradhar,Armando J L Pombeiro,José Armando L da Silva
  • Publisher : Royal Society of Chemistry
  • Release : 11 November 2020
GET THIS BOOKVanadium Catalysis

Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast. Bringing together the research on the catalytic uses of this element into one

The Development of Catalysis

The Development of Catalysis
  • Author : Adriano Zecchina,Salvatore Califano
  • Publisher : John Wiley & Sons
  • Release : 03 April 2017
GET THIS BOOKThe Development of Catalysis

From the onset to the first large scale industrial processes : the origin of the catalytic era -- Historical development of theories of catalysis -- Catalytic processes associated with hydrocarbons and petroleum industry -- Surface science methods in the second half of the XX century -- The development of homogeneous and organo catalysis -- Material science and catalysis design -- Photocatalysis -- Enzymatic catalysis -- Miscellanea