Carbon Functional Organosilicon Compounds

The term "carbon-functional organosilicon compound" is used for organosilicon compounds in which a functional group is bonded to an organic moiety that is in turn con nected to silicon via a Si-C bond. Thus, only Si-Cn-Y com pounds (Y designates a functional group) will be discussed in this book 1 Si-O-Cn-Y compounds will in general not be considered, although the latter group does include a large number of natural substances containing silylated hydroxyl groups. (Because of the differing importance of various Y groups, the reader will find some deviation from this restriction). Finally, compounds containing a silyl group as the functional group are not considered. An overview of the field of organosilicon chemistry would show that in the last several decades the commercial synthesis of organosilicon products has increased substan tially, both in annual production and also in the increasing variety of compounds produced. This increase in the number of commercially available carbon-functional monomers and polymers (silicone polymers) is most remarkable and is occurring because new applications are continually being found for these compounds. As might be expected, the number of publications in this field is also increasing. The important position of silicon in the periodic table - between carbon, aluminum, and phosphorus - means that an understanding of the nature of the bonds in organosilicon compounds is quite important in order to understand the bonding in these other areas.

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  • Author : Vaclav Chvalovsky
  • Publisher : Springer Science & Business Media
  • Pages : 303 pages
  • ISBN : 1475703813
  • Rating : 4/5 from 21 reviews
CLICK HERE TO GET THIS BOOKCarbon Functional Organosilicon Compounds

Carbon-Functional Organosilicon Compounds

Carbon-Functional Organosilicon Compounds
  • Author : Vaclav Chvalovsky
  • Publisher : Springer Science & Business Media
  • Release : 06 December 2012
GET THIS BOOKCarbon-Functional Organosilicon Compounds

The term "carbon-functional organosilicon compound" is used for organosilicon compounds in which a functional group is bonded to an organic moiety that is in turn con nected to silicon via a Si-C bond. Thus, only Si-Cn-Y com pounds (Y designates a functional group) will be discussed in this book 1 Si-O-Cn-Y compounds will in general not be considered, although the latter group does include a large number of natural substances containing silylated hydroxyl groups. (Because of the differing importance of various

Organosilicon Compounds

Organosilicon Compounds
  • Author : Vladimir Ya Lee
  • Publisher : Academic Press
  • Release : 25 September 2017
GET THIS BOOKOrganosilicon Compounds

Organosilicon Compounds: Experiment (Physico-Chemical Studies) and Applications, volume 2, also contains two parts. In its first part, Experiment (Physico-Chemical Studies), the application of modern instrumental tools (such as X-ray crystallography, 29Si NMR spectroscopy, UV-Photoelectron Spectroscopy, and other methods) for assessing the structures of organosilicon compounds is described. The second part, Applications, reviews the current research in the field of material science, specifically the use of organosilicon compounds in synthetic chemistry directed towards the creation of new materials. Organosilicon Compounds: From Theory

Organosilicon Compounds

Organosilicon Compounds
  • Author : Vladimir Ya Lee
  • Publisher : Academic Press
  • Release : 22 August 2017
GET THIS BOOKOrganosilicon Compounds

Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area

Silicon in Organic Synthesis

Silicon in Organic Synthesis
  • Author : Ernest W. Colvin
  • Publisher : Butterworth-Heinemann
  • Release : 22 October 2013
GET THIS BOOKSilicon in Organic Synthesis

Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a “ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of α-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon;

Organosilicon Chemistry

Organosilicon Chemistry
  • Author : Tamejiro Hiyama,Martin Oestreich
  • Publisher : John Wiley & Sons
  • Release : 07 January 2020
GET THIS BOOKOrganosilicon Chemistry

Provides a unique summary of important catalytic reactions in the presence of silicon A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant