Pincer Metal Complexes

Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems transforming hydrocarbons and their derivatives from an synthetic and mechanistic point of view. The success stories of pincer-metal systems are discussed, as well as current and future challenges. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. It is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry. Covers applications of pincer-metal complexes in organic transformations Includes pincer-group 8 and 9 metal complexes for alkane dehydrogenations Features a discussion of pincer-metal complexes for dehydrogenation of functionalized hydrocarbons, and electro-catalytic transformations

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  • Author : Akshai Kumar Alape Seetharam
  • Publisher : Elsevier
  • Pages : 270 pages
  • ISBN : 9780128220917
  • Rating : 4/5 from 21 reviews
CLICK HERE TO GET THIS BOOKPincer Metal Complexes

Pincer-Metal Complexes

Pincer-Metal Complexes
  • Author : Akshai Kumar Alape Seetharam
  • Publisher : Elsevier
  • Release : 15 October 2021
GET THIS BOOKPincer-Metal Complexes

Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems transforming hydrocarbons and their derivatives from an synthetic and mechanistic point of view. The success stories of pincer-metal systems are discussed, as well as current and future challenges. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also

The Chemistry of Pincer Compounds

The Chemistry of Pincer Compounds
  • Author : David Morales-Morales,Craig G.M. Jensen
  • Publisher : Elsevier
  • Release : 11 August 2011
GET THIS BOOKThe Chemistry of Pincer Compounds

Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties. The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide

The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications

The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications
  • Author : Gerard van Koten,Robert A Gossage
  • Publisher : Springer
  • Release : 27 August 2015
GET THIS BOOKThe Privileged Pincer-Metal Platform: Coordination Chemistry & Applications

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of

Organometallic Pincer Chemistry

Organometallic Pincer Chemistry
  • Author : Gerard van Koten,David Milstein
  • Publisher : Springer
  • Release : 17 September 2012
GET THIS BOOKOrganometallic Pincer Chemistry

Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and

Pincer and Pincer-Type Complexes

Pincer and Pincer-Type Complexes
  • Author : Kálmán J. Szabó
  • Publisher : John Wiley & Sons
  • Release : 25 August 2014
GET THIS BOOKPincer and Pincer-Type Complexes

This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis.

Pincer Compounds

Pincer Compounds
  • Author : David Morales-Morales
  • Publisher : Elsevier
  • Release : 11 April 2018
GET THIS BOOKPincer Compounds

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this

Synthesis of Pincer-type NHC Ligands with Phosphorus Functionalities and Their Ag(I), Cu(I) and Ir(I/III) Organometallic Complexes

Synthesis of Pincer-type NHC Ligands with Phosphorus Functionalities and Their Ag(I), Cu(I) and Ir(I/III) Organometallic Complexes
  • Author : Xianghao Liu
  • Publisher : Unknown Publisher
  • Release : 09 May 2021
GET THIS BOOKSynthesis of Pincer-type NHC Ligands with Phosphorus Functionalities and Their Ag(I), Cu(I) and Ir(I/III) Organometallic Complexes

Although the first metal complexes with the cyclometalated PCP pincer ligands (Figure 1a) were reported about 30 years ago, it is still a hot and fast developing topic covering all aspects of chemistry: mechanistic, structural, catalytic, synthetic, theoretical, and coordination studies. Pincer-based metal complexes possess a unique balance of stability and reactivity that can be controlled by systematic ligand modifications and variation of the metal centre.Numerous metal complexes with related pincer-type NHC ligands (Figure 1b) have been reported and well

Organometallic Chemistry and Catalysis

Organometallic Chemistry and Catalysis
  • Author : Didier Astruc
  • Publisher : Springer Science & Business Media
  • Release : 02 August 2007
GET THIS BOOKOrganometallic Chemistry and Catalysis

This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the

Organotransition Metal Chemistry: From Bonding to Catalysis

Organotransition Metal Chemistry: From Bonding to Catalysis
  • Author : John F. Hartwig
  • Publisher : Univ Science Books
  • Release : 10 February 2010
GET THIS BOOKOrganotransition Metal Chemistry: From Bonding to Catalysis

Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring

Bifunctional Molecular Catalysis

Bifunctional Molecular Catalysis
  • Author : Takao Ikariya,Masakatsu Shibasaki
  • Publisher : Springer
  • Release : 24 June 2011
GET THIS BOOKBifunctional Molecular Catalysis

Masakatsu Shibasaki, Motomu Kanai, Shigeki Matsunaga, and Naoya Kumagai: Multimetallic Multifunctional Catalysts for Asymmetric Reactions.- Takao Ikariya: Bifunctional transition metal-based molecular catalysts for asymmetric syntheses.- Chidambaram Gunanathan and David Milstein: Bond Activation by Metal-Ligand Cooperation: Design of ”Green” Catalytic Reactions Based on Aromatization-Dearomatization of Pincer Complexes.- Madeleine C. Warner, Charles P. Casey, and Jan-E. Bäckvall: Shvo’s Catalyst in Hydrogen Transfer Reactions.- Noritaka Mizuno, Keigo Kamata, and Kazuya Yamaguchi: Liquid-Phase Selective Oxidation by Multimetallic Active

Enantioselective Organocatalysis

Enantioselective Organocatalysis
  • Author : Peter I. Dalko
  • Publisher : John Wiley & Sons
  • Release : 17 April 2007
GET THIS BOOKEnantioselective Organocatalysis

In this reference leaders at the forefront of research provide an insight into one of the hottest topics in organic synthesis, focusing on the most important enantioselective reactions. Clearly structured, each entry begins with a concise introduction, including a mechanistic discussion of the reaction, followed by preparative guidelines for newcomers, such as carefully selected working procedures with critical notes for bench chemists, rules of thumb and tips and tricks.

Fragments of Fullerenes and Carbon Nanotubes

Fragments of Fullerenes and Carbon Nanotubes
  • Author : Marina A. Petrukhina,Lawrence T. Scott
  • Publisher : John Wiley & Sons
  • Release : 01 November 2011
GET THIS BOOKFragments of Fullerenes and Carbon Nanotubes

This book is the first of its kind to reflect upon the intense and rapidly growing interest in open geodesic polyaromatic molecules, specifically focusing on their synthesis and reactivity in metal binding reactions. The book broadly covers all aspects related to the fullerene fragment chemistry: current synthetic techniques, description of the available members of this new family (which has grown to more than two dozens members, with none being available commercially), molecular geometry and trends in the solid state packing,

Transition Metal-Dinitrogen Complexes

Transition Metal-Dinitrogen Complexes
  • Author : Yoshiaki Nishibayashi
  • Publisher : John Wiley & Sons
  • Release : 06 May 2019
GET THIS BOOKTransition Metal-Dinitrogen Complexes

A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups. With contributions from noted experts in the field, Transition Metal-Dinitrogen Complexes offers an important guide and comprehensive resource to the most recent research and developments on the