Rearrangements with Migration to Electrophilic Heteroatomic Centers

Rearrangements with Migration to Electrophilic Heteroatomic Centers: Timeless Classics in Organic Synthesis covers the basic principles and synthetic applications of a critically important class of organic reactions that date back to the founding period of organic chemistry. These reactions are not only of historical and pedagogical interest, but also have great practical value to this day, being inevitable in any strategy concerning the introduction of nitrogen and oxygen functionality. The book is made up of three parts, dealing with the Beckmann reaction, the Hoffmann family of reactions and the Baeyer-Villiger reaction. Each part begins with a brief historical introduction followed by a mechanistic discussion. The synthetic applications are then discussed in detail, focusing on current developments and improvements. The book strikes a balance between delineation and exhaustiveness, with up-to-date refences for readers requiring in-depth coverage. Relevant industrial applications, including pharmaceutical processes, are included. This reference will be a key resource for organic synthesis researchers and students, working in academia and industry. Summarizes mechanistic background with an emphasis on synthetic applications Up to date references allow for locating original papers for experimental procedures Applications in the synthesis of complex molecules and natural products are included to judge the scope and limitations of each reaction

Produk Detail:

  • Author : Sosale Chandrasekhar
  • Publisher : Elsevier
  • Pages : 300 pages
  • ISBN : 9780128237434
  • Rating : 4/5 from 21 reviews
CLICK HERE TO GET THIS BOOKRearrangements with Migration to Electrophilic Heteroatomic Centers

Rearrangements with Migration to Electrophilic Heteroatomic Centers

Rearrangements with Migration to Electrophilic Heteroatomic Centers
  • Author : Sosale Chandrasekhar
  • Publisher : Elsevier
  • Release : 15 January 2022
GET THIS BOOKRearrangements with Migration to Electrophilic Heteroatomic Centers

Rearrangements with Migration to Electrophilic Heteroatomic Centers: Timeless Classics in Organic Synthesis covers the basic principles and synthetic applications of a critically important class of organic reactions that date back to the founding period of organic chemistry. These reactions are not only of historical and pedagogical interest, but also have great practical value to this day, being inevitable in any strategy concerning the introduction of nitrogen and oxygen functionality. The book is made up of three parts, dealing with the

Modern Physical Organic Chemistry

Modern Physical Organic Chemistry
  • Author : Eric V. Anslyn,Dennis A. Dougherty
  • Publisher : University Science Books
  • Release : 28 June 2022
GET THIS BOOKModern Physical Organic Chemistry

In additionto covering thoroughly the core areas of physical organic chemistry -structure and mechanism - this book will escort the practitioner of organic chemistry into a field that has been thoroughlyupdated.

Studies in Natural Products Chemistry

Studies in Natural Products Chemistry
  • Author : Shazia Anjum,Elena Soriano,José Luis Marco-Contelles
  • Publisher : Elsevier Inc. Chapters
  • Release : 25 June 2013
GET THIS BOOKStudies in Natural Products Chemistry

Molecular rearrangements occupy center stage in the development of organic synthesis and, consequently, in the impressive achievements that have resulted in the total synthesis of many complex natural products in the last decades. The purpose of this chapter, in this volume of a book series dedicated to the Studies in Natural Product Chemistry, is to show a set of selected and organized molecular rearrangements based on a personal choice of expertise related to the synthesis of complex bioactive molecules. Our

Organic Syntheses Based on Name Reactions and Unnamed Reactions

Organic Syntheses Based on Name Reactions and Unnamed Reactions
  • Author : Alfred Hassner,C Stumer
  • Publisher : Elsevier
  • Release : 22 October 2013
GET THIS BOOKOrganic Syntheses Based on Name Reactions and Unnamed Reactions

Synthetically useful organic reactions or reagents are often referred to by the name of the discoverer(s) or developer(s). Older name reactions are described in text books, but more recently developed synthetically useful reactions that may have been associated occasionally with a name are not always well known. For neither of the above are experimental procedures or references easy to find. In this monograph approximately 500 name reactions are included, of which over 200 represent newer name reactions and modern reagents.

The Claisen Rearrangement

The Claisen Rearrangement
  • Author : Martin Hiersemann,Udo Nubbemeyer
  • Publisher : John Wiley & Sons
  • Release : 27 February 2007
GET THIS BOOKThe Claisen Rearrangement

The first comprehensive coverage of all facets of the Claisen rearrangement and its variants. As such, this book helps synthetic chemists to exploit the vast potential of this elegant C-C linking reaction, discusses a wealth of catalytic options, and gives those more theory-minded chemists a detailed insight into the mechanistic aspects of the Claisen rearrangement. An invaluable source of information and a ready reference for all organic and catalytic chemists, as well as those working with/on organometallics, and in

The Isoquinoline Alkaloids

The Isoquinoline Alkaloids
  • Author : K. W. Bentley
  • Publisher : Elsevier
  • Release : 24 April 2014
GET THIS BOOKThe Isoquinoline Alkaloids

The Isoquinoline Alkaloids: A Course in Organic Chemistry is a description of the chemical structures of alkaloids. The book discusses the processes for degradation of isoquinoline alkaloids to recognizable compounds such as oxidation and exhaustive methylation. The associated processes in removing the nitrogen atom are also explained. The commonly used Hofmann process and the interpretation of its result are evaluated in the degradation of alkaloids. The cactus ""pellote"" used by Mexican Indians to induce hallucinatory experiences is examined. The active

Vinyl Cations

Vinyl Cations
  • Author : Peter Stang
  • Publisher : Elsevier
  • Release : 02 December 2012
GET THIS BOOKVinyl Cations

Vinyl Cations provides a comprehensive and detailed treatment of the reactive intermediate in which the electron-deficient carbon is an integral part of a ? unsaturation. This book emphasizes that the reaction through vinyl cations is a viable pathway among the multitude of mechanistic routes for vinylic substitution. The aryl, ethynyl, and allenyl cations from the viewpoint of direct solvolytic generation from appropriate allenyl precursors are briefly discussed. Other topics include the preparative aspects of electrophilic additions to alkynes, participation of allenyl

Writing Reaction Mechanisms in Organic Chemistry

Writing Reaction Mechanisms in Organic Chemistry
  • Author : Audrey Miller,Philippa H. Solomon
  • Publisher : Elsevier
  • Release : 02 December 2012
GET THIS BOOKWriting Reaction Mechanisms in Organic Chemistry

Presentation is clear and instructive: students will learn to recognize that many of the reactions in organic chemistry are closely related and not independent facts needing unrelated memorization. The book emphasizes that derivation of a mechanism is not a theoretical procedure, but a means of applying knowledge of other similar reactions and reaction conditions to the new reaction. n Brief summaries of required basic knowledge of organic structure, bonding, stereochemistry, resonance, tautomerism, and molecular orbital theory n Definitions of essential

Organic Reaction Mechanisms

Organic Reaction Mechanisms
  • Author : Michael Edenborough
  • Publisher : CRC Press
  • Release : 21 December 2017
GET THIS BOOKOrganic Reaction Mechanisms

This text is designed to teach students how to write organic reaction mechanisms. It starts from the absolute basics - counting the numbers of electrons around a simple atom. Then, in small steps, the text progresses to advanced mechanisms. the end, all the major mechanistic routes have been covered. The text is in the form of interactive sections, which are designed to facilitate the assimilation of the information conveyed, so that by the end the student should already know the

Silicon in Organic Synthesis

Silicon in Organic Synthesis
  • Author : Ernest W. Colvin
  • Publisher : Butterworth-Heinemann
  • Release : 22 October 2013
GET THIS BOOKSilicon in Organic Synthesis

Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a “ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of α-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon;

Comprehensive Organic Synthesis

Comprehensive Organic Synthesis
  • Author : Anonim
  • Publisher : Newnes
  • Release : 14 February 2014
GET THIS BOOKComprehensive Organic Synthesis

The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on

The Art of Writing Reasonable Organic Reaction Mechanisms

The Art of Writing Reasonable Organic Reaction Mechanisms
  • Author : Robert B. Grossman
  • Publisher : Springer Science & Business Media
  • Release : 31 July 2007
GET THIS BOOKThe Art of Writing Reasonable Organic Reaction Mechanisms

Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered

Advanced Organic Chemistry

Advanced Organic Chemistry
  • Author : Francis A. Carey,Richard J. Sundberg
  • Publisher : Springer Science & Business Media
  • Release : 27 June 2007
GET THIS BOOKAdvanced Organic Chemistry

The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and

Advances in Heterocyclic Chemistry

Advances in Heterocyclic Chemistry
  • Author : Anonim
  • Publisher : Elsevier
  • Release : 04 July 2000
GET THIS BOOKAdvances in Heterocyclic Chemistry

Established in 1960, Advances in Heterocyclic Chemistry is the definitive serial in the area--one of great importance to organic chemists, polymer chemists, and many biological scientists. Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight and yield an understanding of how the chemistry drives the properties.

Comprehensive Organic Functional Group Transformations II

Comprehensive Organic Functional Group Transformations II
  • Author : Anonim
  • Publisher : Elsevier
  • Release : 16 December 2004
GET THIS BOOKComprehensive Organic Functional Group Transformations II

Comprehensive Organic Functional Group Transformations II (COFGT-II) will provide the first point of entry to the literature for all scientists interested in chemical transformations. Presenting the vast subject of organic synthesis in terms of the introduction and interconversion of all known functional groups, COFGT-II provides a unique information source documenting all methods of efficiently performing a particular transformation. Organised by the functional group formed, COFGT-II consists of 144 specialist reviews, written by leading scientists who evaluate and summarise the methods available